APPENDIX E
<br />2015 MINNESOTA STATE FIRE CODE 481
<br />chloro)-penta-s-triazinetrione, nitric acid, (fuming -
<br />more than 86 percent concentration), perchloric acid
<br />solutions (60 percent to 72 percent by weight),
<br />potassium bromate, potassium chlorate, potassium
<br />dichloro-s-triazinetrione (potassium dichloro-isocy-
<br />anurate), sodium bromate, sodium chlorate, sodium
<br />chlorite (over 40 percent by weight) and sodium
<br />dichloro-s-triazinetrione (sodium dichloro-isocyanu-
<br />rate).
<br />Class 2: barium bromate, barium chlorate, barium
<br />hypochlorite, barium perchlorate, barium permanga-
<br />nate, 1-bromo-3-chloro-5, 5-dimethylhydantoin, cal-
<br />cium chlorate, calcium chlorite, calcium
<br />hypochlorite (50 percent or less by weight), calcium
<br />perchlorate, calcium permanganate, chromium triox-
<br />ide (chromic acid), copper chlorate, halane (1, 3-di-
<br />chloro-5, 5-dimethylhydantoin), hydrogen peroxide
<br />(greater than 27.5 percent up to 52 percent), lead
<br />perchlorate, lithium chlorate, lithium hypochlorite
<br />(more than 39 percent available chlorine), lithium
<br />perchlorate, magnesium bromate, magnesium chlo-
<br />rate, magnesium perchlorate, mercurous chlorate,
<br />nitric acid (more than 40 percent but less than 86
<br />percent), perchloric acid solutions (more than 50
<br />percent but less than 60 percent), potassium perchlo-
<br />rate, potassium permanganate, potassium peroxide,
<br />potassium superoxide, silver peroxide, sodium chlo-
<br />rite (40 percent or less by weight), sodium perchlo-
<br />rate, sodium perchlorate monohydrate, sodium
<br />permanganate, sodium peroxide, strontium chlorate,
<br />strontium perchlorate, thallium chlorate, trichloro-s-
<br />triazinetrione (trichloroisocyanuric acid), urea
<br />hydrogen peroxide, zinc bromate, zinc chlorate and
<br />zinc permanganate.
<br />Class 1: all inorganic nitrates (unless otherwise clas-
<br />sified), all inorganic nitrites (unless otherwise classi-
<br />fied), ammonium persulfate, barium peroxide,
<br />calcium peroxide, hydrogen peroxide solutions
<br />(greater than 8 percent up to 27.5 percent), lead
<br />dioxide, lithium hypochlorite (39 percent or less
<br />available chlorine), lithium peroxide, magnesium
<br />peroxide, manganese dioxide, nitric acid (40 percent
<br />concentration or less), perchloric acid solutions (less
<br />than 50 percent by weight), potassium dichromate,
<br />potassium percarbonate, potassium persulfate,
<br />sodium carbonate peroxide, sodium dichloro-s-tri-
<br />azinetrione dihydrate, sodium dichromate, sodium
<br />perborate (anhydrous), sodium perborate monohy-
<br />drate, sodium perborate tetra-hydrate, sodium per-
<br />carbonate, sodium persulfate, strontium peroxide
<br />and zinc peroxide.
<br />E102.1.8 Organic peroxides. Organic peroxides contain
<br />the double oxygen or peroxy (-o-o) group. Some are flam-
<br />mable compounds and subject to explosive decomposi-
<br />tion. They are available as:
<br />1. Liquids.
<br />2. Pastes.
<br />3. Solids (usually finely divided powers).
<br />E102.1.8.1 Classification of organic peroxides
<br />according to hazard.
<br />Unclassified: Unclassified organic peroxides are
<br />capable of detonation and are regulated in accor-
<br />dance with Chapter 56 of the International Fire
<br />Code.
<br />Class I: acetyl cyclohexane sulfonyl 60-65 percent
<br />concentration by weight, fulfonyl peroxide, benzoyl
<br />peroxide over 98 percent concentration, t-butyl
<br />hydroperoxide 90 percent, t-butyl peroxyacetate 75
<br />percent, t-butyl peroxyisopropylcarbonate 92 per-
<br />cent, diisopropyl peroxydicarbonate 100 percent, di-
<br />n-propyl peroxydicarbonate 98 percent, and di-n-
<br />propyl peroxydicarbonate 85 percent.
<br />Class II: acetyl peroxide 25 percent, t-butyl hydrop-
<br />eroxide 70 percent (with DTBP and t-BuOH dilu-
<br />ents), t-butyl peroxybenzoate 98 percent, t-butyl
<br />peroxy-2-ethylhexanoate 97 percent, t-butyl peroxy-
<br />isobutyrate 75 percent, t-butyl peroxyisopropyl-car-
<br />bonate 75 percent, t-butyl peroxypivalate 75
<br />percent, dybenzoyl peroxydicarbonate 85 percent,
<br />di-sec-butyl peroxydicarbonate 98 percent, di-sec-
<br />butyl peroxydicarbonate 75 percent, 1,1-di-(t-
<br />butylperoxy)-3,5,5-trimethyecyclohexane 95 per-
<br />cent, di-(2-ethythexyl) peroxydicarbonate 97 per-
<br />cent, 2,5-dymethyl-2-5 di (benzoylperoxy) hexane
<br />92 percent, and peroxyacetic acid 43 percent.
<br />Class III: acetyl cyclohexane sulfonal peroxide 29
<br />percent, benzoyl peroxide 78 percent, benzoyl per-
<br />oxide paste 55 percent, benzoyl peroxide paste 50
<br />percent peroxide/50 percent butylbenzylphthalate
<br />diluent, cumene hydroperoxide 86 percent, di-(4-
<br />butylcyclohexyl) peroxydicarbonate 98 percent, t-
<br />butyl peroxy-2-ethylhexanoate 97 percent, t-butyl
<br />peroxyneodecanoate 75 percent, decanoyl peroxide
<br />98.5 percent, di-t-butyl peroxide 99 percent, 1,1-di-
<br />(t-butylperoxy)3,5,5-trimethylcyclohexane 75 per-
<br />cent, 2,4-dichlorobenzoyl peroxide 50 percent, di-
<br />isopropyl peroxydicarbonate 30 percent, 2,-5-di-
<br />methyl-2,5-di-(2-ethylhexanolyperoxy)-hexane 90
<br />percent, 2,5-dimethyl-2,5-di-(t-butylperoxy) hexane
<br />90 percent and methyl ethyl ketone peroxide 9 per-
<br />cent active oxygen diluted in dimethyl phthalate.
<br />Class IV: benzoyl peroxide 70 percent, benzoyl per-
<br />oxide paste 50 percent peroxide/15 percent water/35
<br />percent butylphthalate diluent, benzoyl peroxide
<br />slurry 40 percent, benzoyl peroxide powder 35 per-
<br />cent, t-butyl hydroperoxide 70 percent, (with water
<br />diluent), t-butyl peroxy-2-ethylhexanoate 50 per-
<br />cent, decumyl peroxide 98 percent, di-(2-ethylhexal)
<br />peroxydicarbonate 40 percent, laurel peroxide 98
<br />percent, p-methane hydroperoxide 52.5 percent,
<br />methyl ethyl ketone peroxide 5.5 percent active oxy-
<br />gen and methyl ethyl ketone peroxide 9 percent
<br />active oxygen diluted in water and glycols.
<br />Class V: benzoyl peroxide 35 percent, 1,1-di-t-
<br />butyl peroxy 3,5,5-trimethylcyclohexane 40 per-
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