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CC WORKSESSION 12142015
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CC WORKSESSION 12142015
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<br />hydroxyl radicals due to the water matrix, fewer radicals are available to react with the <br />contaminant. <br />These water quality parameters impact various reactors and lamp types differently. <br />• Lamp age. E EO increases as lamps age. That is, more power is required at the end of the lamp <br />life than at the beginning in order to achieve the same effectiveness. This is because the <br />lamp’s UVC electrical efficiency decreases over time. <br />• Flow rate. In general, because E EO is normalized by the flow rate, reactor systems treating <br />different flow rates can be compared. However, such comparisons should be made cautiously <br />as empirical evidence and theoretical analysis have shown that the E EO value decreases to an <br />asymptotic value as flow rate increases. This is due to increases in reactor hydraulic <br />efficiency with increases in turbulence and mixing at higher flow rates. Reactors must be <br />specifically designed for certain conditions, including flow rates. <br />• Hydrogen Peroxide Concentration. E EO is a strong function of H 2 O 2 concentration. The <br />irradiation of H 2 O 2 produces hydroxyl radicals which accelerate the degradation of <br />contaminants in the water. The higher the H 2 O 2 concentration the more UV it absorbs and the <br />more radicals are formed. However, H 2 O 2 itself scavenges hydroxyl radicals. Therefore, the <br />greater the concentration of H 2 O 2 , the greater the scavenging of hydroxyl radicals. Therefore, <br />E EO varies inversely with H2 O 2 concentration but this is not a linear relationship. <br />• Contaminant. Different contaminants will have a different E EO value in the same reactor in <br />water with the same quality. This is due to differences in the quantum yield, molar absorption <br />coefficient, and hydroxyl radical reaction rate (i.e., their fundamental kinetic parameters). <br /> <br /> <br /> <br /> <br />3 PILOT SYSTEM DESIGN <br />3.1 APPROACH TO THE UV-AOP STUDY <br /> <br />While it was the objective of this study to demonstrate the capability of the UV/H 2 O 2 system to treat <br />1,4-dioxane present in the St. Anthony groundwater, it was decided to inject additional 1,4-dioxane <br />upstream of the UV reactor. This was done to allow the UV/H 2 O 2 pilot system to demonstrate <br />treatment of 1,4-dioxane that exceeds 3-log (i.e., >99.9%) reduction. <br /> <br />The primary water quality parameters that influence the efficiency of UV/H 2 O 2 treatment are the UV <br />transmittance (UVT) of the water and its hydroxyl radical scavenging demand. The UVT of the water <br />affects the efficiency of delivering the UV photons to the target chemical (i.e., H 2 O 2 ). Similarly, the <br />hydroxyl radical scavenging capacity quantifies the overall demand for hydroxyl radicals due to all <br />constituents present in the water. <br /> <br />Trojan received a water sample from St. Anthony in July 2015. The sample was collected upstream of <br />the GAC filters and is representative of the water that would supply the pilot system. This sample was <br />evaluated for the water quality parameters that potentially impact the efficiency of UV/H 2 O 2 <br />treatment. Figure 1 presents a summary of the data for the St. Anthony water sample. The key <br />conclusions from the water quality analysis are that the UVT is very high at 96.3% and the hydroxyl <br />radical scavenging capacity is moderately high. The moderately high hydroxyl radical scavenging <br />capacity is due to the relatively high alkalinity and resulting bicarbonate ion concentration. These <br />results are consistent with the measurement of pH, alkalinity and DOC and together provide a strong <br /> 5
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