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CC WORKSESSION 12142015
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CC WORKSESSION 12142015
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<br />causing compounds, algal toxins, pharmaceuticals and personal care products, endocrine <br />disrupting compounds, NDMA and 1,4-Dioxane. Numerous systems, including Tucson’s 5,800 <br />gpm airport remediation project utilizing the TrojanUV Phox D72AL75 installation, the 100 MGD <br />Groundwater Replenishment System in Orange County California and the 50 MGD UV oxidation <br />system in Aurora, Colorado are designed for low-pressure UV oxidation of various contaminants. <br /> <br /> <br />6.1 DESIGN CRITERIA <br /> <br />The full-scale design criteria together with measured water quality are summarized in Table 3. <br /> <br /> <br />Table 3: City of St. Anthony Water Village Treatment System Design Specifications <br />UV SYSTEM DESIGN SPECIFICATIONS <br />Design Flow 3000 gpm <br />Average Flow 1250 gpm <br />Target 1,4-dioxane Log Reduction 2.0-Log <br />Measured UV Transmittance 96% <br /> <br />The model output for the projected water quality at the peak flow conditions (i.e., 3000 gpm at 96% <br />UVT) provides an electrical energy per order (E EO ) value of 0.41 kWh/kgal/order for 1,4-dioxane <br />when 18 ppm of H 2 O 2 is present. This value is associated with the UV output at the end-of-lamp-life <br />(EOLL) condition as well as an appropriate level of conservatism. Trojan has proposed to reduce 1,4- <br />dioxane by 2.0-log (i.e., 99.0%) in this stream with 2 parallel trains of 2 TrojanUVPhox™ D72AL75 <br />reactors plus one redundant train. This system is described in a separate proposal. <br /> <br />While Trojan’s preferred approach to sizing UV-AOP systems is to rely upon our proven mechanistic <br />sizing model, as described above, there are several aspects of the empirical scale-up approach that <br />should be discussed. Full-scale UV reactors typically have superior treatment efficiency compared <br />with pilot-scale reactors for the following reasons. <br />In UV-based AOP systems, most UV photons that are transmitted through the water and reach the wall <br />of the reactor are absorbed by the wall material and do not contribute to the contaminant treatment <br />process. This loss of photons at the reactor wall and other surfaces within the UV reactor represents an <br />inefficiency of the reactor. Conversely, if a large fraction of photons that are emitted by the lamps are <br />absorbed by constituents in the water, a desired result, then the reactor is said to have high absorption <br />efficiency. This reactor absorption efficiency can be increased by providing a longer pathlength for the <br />photons to travel before they reach a surface. Similarly, reactors typically have higher efficiencies <br />when operated at higher flow rates. This is a result of better hydraulic performance (i.e., mixing) that <br />better approaches the ideal plug flow behaviour. The result of these phenomena is that the relatively <br />small pilot reactors operated at relatively low flows generally have a lower efficiency (i.e., higher E EO ) <br />than larger full-scale reactors. It is therefore, not recommended to assume that a full-scale system will <br />have the same E EO as a pilot-scale system when operated with the same water quality and H 2 O 2 dose. <br /> <br /> 18
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